Least-squares support vector machines modelization for time-resolved spectroscopy.

نویسندگان

  • Fabien Chauchard
  • Sylvie Roussel
  • Jean-Michel Roger
  • Véronique Bellon-Maurel
  • Christoffer Abrahamsson
  • Tomas Svensson
  • Stefan Andersson-Engels
  • Sune Svanberg
چکیده

By use of time-resolved spectroscopy it is possible to separate light scattering effects from chemical absorption effects in samples. In the study of propagation of short light pulses in turbid samples the reduced scattering coefficient and the absorption coefficient are usually obtained by fitting diffusion or Monte Carlo models to the measured data by use of numerical optimization techniques. In this study we propose a prediction model obtained with a semiparametric modeling technique: the least-squares support vector machines. The main advantage of this technique is that it uses theoretical time dispersion curves during the calibration step. Predictions can then be performed by use of data measured on different kinds of sample, such as apples.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Identification and Adaptive Position and Speed Control of Permanent Magnet DC Motor with Dead Zone Characteristics Based on Support Vector Machines

In this paper a new type of neural networks known as Least Squares Support Vector Machines which gained a huge fame during the recent years for identification of nonlinear systems has been used to identify DC motor with nonlinear dead zone characteristics. The identified system after linearization in each time span, in an online manner provide the model data for Model Predictive Controller of p...

متن کامل

Least-squares support vector machine and its application in the simultaneous quantitative spectrophotometric determination of pharmaceutical ternary mixture

This paper proposes the least-squares support vector machine (LS-SVM) as an intelligent method applied on absorption spectra for the simultaneous determination of paracetamol (PCT), caffeine (CAF) and ibuprofen (IB) in Novafen. The signal to noise ratio (S/N) increased. Also, In the LS - SVM model, Kernel parameter (σ2) and capacity factor (C) were optimized. Excellent prediction was shown usin...

متن کامل

Partial least squares- least squares- support vector machine modeling of ATR-IR as a spectrophotometric method for detection and determination of iron in pharmaceutical formulations

Iron is an essential element used as supplement in different dosage-forms. Different time and expenditure-consuming methods introduced for detection and determination of elemental ions such as atomic absorption. In this research, two different and routine methods containing ATR-IR and atomic absorption were applied to define the amount of iron in 198 samples containing different concentrations ...

متن کامل

Partial least squares- least squares- support vector machine modeling of ATR-IR as a spectrophotometric method for detection and determination of iron in pharmaceutical formulations

Iron is an essential element used as supplement in different dosage-forms. Different time and expenditure-consuming methods introduced for detection and determination of elemental ions such as atomic absorption. In this research, two different and routine methods containing ATR-IR and atomic absorption were applied to define the amount of iron in 198 samples containing different concentrations ...

متن کامل

Least Squares Support Vector Machine for Constitutive Modeling of Clay

Constitutive modeling of clay is an important research in geotechnical engineering. It is difficult to use precise mathematical expressions to approximate stress-strain relationship of clay. Artificial neural network (ANN) and support vector machine (SVM) have been successfully used in constitutive modeling of clay. However, generalization ability of ANN has some limitations, and application of...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Applied optics

دوره 44 33  شماره 

صفحات  -

تاریخ انتشار 2005